Development and characterization of cement paste-coated shape-stabilized phase change materials to achieve net zero energy buildings in desert climates

  • Khaled Own Mohaisen orcid

    Interdisciplinary Research Center for Sustainable Energy Systems (IRC-SES), King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

  • Md. Hasan Zahir orcid

    Interdisciplinary Research Center for Sustainable Energy Systems (IRC-SES), King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

  • Kashif Irshad orcid

    Interdisciplinary Research Center for Sustainable Energy Systems (IRC-SES), King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

    Mechanical Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

  • Aasif Helal

    Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC-HTCM), King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

  • M. Nasiruzzaman Shaikh

    Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC-HTCM), King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

Article ID: 2175
Keywords: shape-stabilized PCMs, lightweight aggregates, polyethylene glycol, thermal energy storage concrete, net zero energy buildings

Abstract

The development of shape-stabilized phase change materials (SS-PCMs) and their use in construction materials has demonstrated significant potential for improving building energy efficiency and reducing the power consumption of buildings, particularly in desert climates. Despite these benefits, the widespread application of PCMs in civil infrastructure is hindered by their high cost, preparation complexity, leakage issues, and low thermal conductivity. This study addresses these challenges by employing a low-cost, lightweight aggregate (LWA) as a carrier combined with polyethylene glycol (PEG) to develop an LWA/PEG composite PCM. The PEG was incorporated into the LWA pores using a vacuum impregnation technique. Analysis via X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR) confirmed that the LWA/PEG composite was successfully prepared without any chemical reactions occurring during the process. However, LWA/PEG composite suffers from leakage problems, which limit its use in building applications. Accordingly, a cement paste coating was developed and applied on LWA/PEG to prepare SS-PCM (CLWA) to prevent the leakage of the composite and enhance its thermal conductivity. Moreover, it was noted that the developed CLWA is chemically stable, and it exhibited outstanding thermal stability after 200 cycles of melting and solidification without signs of leakage. These advantageous characteristics indicate that the CLWA developed can be effectively employed to enhance the thermal efficiency of construction materials to achieve net-zero energy in buildings.

Published
2025-10-02
How to Cite
Mohaisen, K. O., Zahir, M. H., Irshad, K., Helal, A., & Shaikh, M. N. (2025). Development and characterization of cement paste-coated shape-stabilized phase change materials to achieve net zero energy buildings in desert climates. Building Engineering, 3(4). https://doi.org/10.59400/be2175
Section
Article

References

[1]Aditya L, Mahlia TMI, Rismanchi B, et al. A review on insulation materials for energy conservation in buildings. Renewable and Sustainable Energy Reviews. 2017; 73: 1352–65.

[2]Fang Y, Memon S, Peng J, et al. Solar thermal performance of two innovative configurations of air-vacuum layered triple glazed windows. Renewable Energy. 2020; 150: 167–75.

[3]Khadiran T, Hussein MZ, Zainal Z, et al. Advanced energy storage materials for building applications and their thermal performance characterization: A review. Renewable and Sustainable Energy Reviews. 2016; 57: 916–28.

[4]Wahid MA, Hosseini SE, Hussen HM, et al. An overview of phase change materials for construction architecture thermal management in hot and dry climate region. Applied Thermal Engineering. 2017; 112: 1240–1259.

[5]Keshteli AN, Sheikholeslami M. Nanoparticle enhanced PCM applications for intensification of thermal performance in building: A review. Journal of Molecular Liquids. 2019; 274: 516–33.

[6]Sharifi S, Saman W, Alemu A. Identification of overheating in the top floors of energy-efficient multilevel dwellings. Energy and Buildings. 2019; 204.

[7]Al Miaari A, Mohaisen KO, Al-Ahmed A, et al. Experimental investigation on thermal management and performance enhancement of photovoltaic panel cooled by a sustainable shape stabilized phase change material. Case Studies in Thermal Engineering. 2025; 67: 105763.

[8]Mohaisen KO, Zahir MH, Maslehuddin M, et al. Development of a shape-stabilized phase change material utilizing natural and industrial byproducts for thermal energy storage in buildings. Journal of Energy Storage. 2022; 50: 104205.

[9]Javadi FS, Metselaar HSC, Ganesan P. Performance improvement of solar thermal systems integrated with phase change materials (PCM), a review. Solar Energy. 2020; 206: 330–52.

[10]Zahir MH, Irshad K, Ibrahim NI, et al. Challenges of the application of PCMs to achieve zero energy buildings under hot weather conditions: A review. Journal of Energy Storage. 2023; 64: 107156.

[11]Zhou D, Zhao CY, Tian Y. Review on thermal energy storage with phase change materials (PCMs) in building applications. Applied Energy. 2012; 92: 593–605.

[12]Gandhi M, Kumar A, Elangovan R, et al. A review on shape-stabilized phase change materials for latent energy storage in buildings. Sustainability. 2020; 12(20): 18.

[13]Zhu N, Li S, Hu P, et al. A review on applications of shape-stabilized phase change materials embedded in building enclosure in recent ten years. Sustainable Cities and Society. 2018; 43: 251–64.

[14]Yu K, Liu Y, Yang Y. Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties. Applied Energy. 2021; 292: 116845.

[15]Almazroui M. Summer maximum temperature over the gulf cooperation council states in the twenty-first century: multimodel simulations overview. Arabian Journal of Geosciences. 2020; 13.

[16]Bruno F, Belusko M, Liu M, et al. Using solid-liquid phase change materials (PCMs) in thermal energy storage systems. Woodhead Publishing; 2015.

[17]Zhang J, Zhang X, Wan Y, et al. Preparation and thermal energy properties of paraffin/halloysite nanotube composite as form-stable phase change material. Solar Energy. 2012; 86(5): 1142–1148.

[18]Xu B, Li Z. Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage. Applied Energy. 2013; 105: 229–237.

[19]Li X, Sanjayan JG, Wilson JL. Fabrication and stability of form-stable diatomite/paraffin phase change material composites. Energy and Buildings. 2014; 76: 284–294.

[20]Li M, Wu Z, Kao H, et al. Experimental investigation of preparation and thermal performances of paraffin/bentonite composite phase change material. Energy Conversion and Management. 2011; 52: 3275–3281.

[21]Lv P, Liu C, Rao Z. Experiment study on the thermal properties of paraffin/kaolin thermal energy storage form-stable phase change materials. Applied Energy. 2016; 182: 475–487.

[22]Memon SA, Liao W, Yang S, et al. Development of composite PCMs by incorporation of paraffin into various building materials. Materials. 2015; 8: 499–518.

[23]Hasan A, Al-Sallal KA, Alnoman H, et al. Effect of phase change materials (PCMs) integrated into a concrete block on heat gain prevention in a hot climate. Sustainability. 2016; 8(10): 1009.

[24]Mohaisen KO, Zahir MH, Al-Dulaijan SU, et al. An innovative lightweight aggregate composite phase change material for thermal energy storage enhancement of concrete under hot weather conditions. Journal of Building Engineering. 2025; 99: 111575.

[25]Kou Y, Wang S, Luo J, et al. Thermal analysis and heat capacity study of polyethylene glycol (PEG) phase change materials for thermal energy storage applications. Journal of Chemical Thermodynamics. 2019; 128: 259–274.

[26]Memon SA, Cui HZ, Zhang H, et al. Utilization of macro encapsulated phase change materials for the development of thermal energy storage and structural lightweight aggregate concrete. Applied Energy. 2015; 139: 43–55.

[27]Cui H, Memon SA, Liu R. Development, mechanical properties and numerical simulation of macro encapsulated thermal energy storage concrete. Energy and Buildings. 2015; 96: 162–714.

[28]Moufti MR, Sabtan AA, El-Mahdy OR, et al. Assessment of the industrial utilization of scoria materials in central Harrat Rahat, Saudi Arabia. Engineering Geology. 2000; 57: 155–162.

[29]Alhozaimy A, Fares G, Alawad OA, et al. Heat of hydration of concrete containing powdered scoria rock as a natural pozzolanic material. Construction and Building Materials. 2015; 81: 113–119.

[30]Juimo Tchamdjou WH, Cherradi T, Abidi ML, et al. Mechanical properties of lightweight aggregates concrete made with Cameroonian volcanic Scoria: Destructive and non-destructive characterization. Journal of Building Engineering. 2018; 16: 134–145.

[31]Bogas JA, Cunha D. Non-structural lightweight concrete with volcanic scoria aggregates for lightweight fill in building’s floors. Construction and Building Materials. 2017; 135: 151–163.

[32]Tchamdjou WHJ, Grigoletto S, Michel F, et al. An investigation on the use of coarse volcanic scoria as sand in Portland cement mortar. Case Studies in Construction Materials. 2017; 7: 191–206.

[33]Song M, Niu F, Mao N, et al. Review on building energy performance improvement using phase change materials. Energy and Buildings. 2018; 158: 776–793.

[34]Konuklu Y, Ostry M, Paksoy HO, et al. Review on using microencapsulated phase change materials (PCM) in building applications. Energy and Buildings. 2015; 106: 134–55.

[35]Soares N, Costa JJ, Gaspar AR, et al. Review of passive PCM latent heat thermal energy storage systems towards buildings’ energy efficiency. Energy and Buildings. 2013; 59: 82–103.

[36]Ramakrishnan S, Sanjayan J, Wang X, et al. A novel paraffin/expanded perlite composite phase change material for prevention of PCM leakage in cementitious composites. Applied Energy. 2015; 157: 85–94.

[37]D’Alessandro A, Pisello AL, Fabiani C, et al. Multifunctional smart concretes with novel phase change materials: Mechanical and thermo-energy investigation. Applied Energy. 2018; 212: 1448–1461.

[38]Wang R, Ren M, Gao X, et al. Preparation and properties of fatty acids based thermal energy storage aggregate concrete. Construction and Building Materials. 2018; 165: 1–10.

[39]Memon SA, Cui H, Lo TY, et al. Development of structural-functional integrated concrete with macro-encapsulated PCM for thermal energy storage. Applied Energy. 2015; 150: 245–257.

[40]Ma Q, Bai M. Mechanical behavior, energy-storing properties and thermal reliability of phase-changing energy-storing concrete. Construction and Building Materials. 2018; 176: 43–49.

[41]Cui H, Memon SA, Liu R. Development, mechanical properties and numerical simulation of macro encapsulated thermal energy storage concrete. Energy and Buildings. 2015; 96: 162–174.

[42]Min HW, Kim S, Kim HS. Investigation on thermal and mechanical characteristics of concrete mixed with shape stabilized phase change material for mix design. Construction and Building Materials. 2017; 149: 749–762.

[43]Niall D, Kinnane O, West RP, et al. Mechanical and thermal evaluation of different types of PCM–concrete composite panels. Journal of Structural Integrity and Maintenance. 2017; 2: 100–108.

[44]Kumar D, Alam M, Sanjayan J, et al. Comparative analysis of form-stable phase change material integrated concrete panels for building envelopes. Case Studies in Construction Materials. 2023; 18: e01737.

[45]Ren M, Liu Y, Gao X. Incorporation of phase change material and carbon nanofibers into lightweight aggregate concrete for thermal energy regulation in buildings. Energy. 2020; 197: 117262.

[46]Lecompte T, Le Bideau P, Glouannec P, et al. Mechanical and thermo-physical behaviour of concretes and mortars containing phase change material. Energy and Buildings. 2015; 94: 52–60.

[47]Gencel O, Ustaoglu A, Benli A, et al. Investigation of physico-mechanical, thermal properties and solar thermoregulation performance of shape-stable attapulgite based composite phase change material in foam concrete. Solar Energy. 2022; 236: 51–62.

[48]Kwon JS, Yun ST, Lee JH, et al. Removal of divalent heavy metals (Cd, Cu, Pb, and Zn) and arsenic(Ⅲ) from aqueous solutions using scoria: Kinetics and equilibria of sorption. Journal of Hazardous Materials. 2010; 174: 307–313.

[49]Seyfi S, Azadmehr AR, Gharabaghi M, et al. Usage of Iranian scoria for copper and cadmium removal from aqueous solutions. Journal of Central South University. 2015; 22: 3760–3769.

[50]Depci T, Efe T, Tapan M, et al. Chemical characterization of Patnos scoria (Aǧri, Turkey) and its usability for production of blended cement. Physicochemical Problems of Mineral Processing. 2012; 48(1): 303–315.

[51]Djobo JNY, Tchadjié LN, Tchakoute HK, et al. Synthesis of geopolymer composites from a mixture of volcanic scoria and metakaolin. Journal of Asian Ceramic Societies. 2014; 2: 387–398.

[52]Liu Z, Wei H, Tang B, et al. Novel light–driven CF/PEG/SiO2 composite phase change materials with high thermal conductivity. Solar Energy Materials and Solar Cells. 2018; 174: 538–544.

[53]Zahir MH, Rahman MM, Irshad K. Shape-Stabilized Phase Change Materials for Solar Energy Storage: MgO and Mg(OH)2 Mixed with Polyethylene Glycol. Nanomaterials. 2019; 9: 1773.

[54]Li H, Chen H, Li X, et al. Development of thermal energy storage composites and prevention of PCM leakage. Applied Energy. 2014; 135: 225–233.

[55]ASTM. Standard Test Method for Specific Gravity and Absorption of Coarse Aggregate. American Society for Testing and Materials; 2001.

[56]Li C, Zhang B, Xie B, et al. Tailored phase change behavior of Na2SO4·10H2O/expanded graphite composite for thermal energy storage. Energy Conversion and Management. 2020; 208: 112586.

[57]Qian T, Li J, Min X, et al. Polyethylene glycol/mesoporous calcium silicate shape-stabilized composite phase change material: Preparation, characterization, and adjustable thermal property. Energy. 2015; 82: 333–340.