Thermodynamic investigation of a diffusion absorption refrigeration system with an isobutane–dimethylformamide–helium working fluid blend

  • Sreenesh Valiyandi orcid

    Division of Mechanical Engineering, School of Engineering, Cochin University of Science and Technology, Ernakulam 682022, India

  • Gireeshkumaran Thampi orcid

    Division of Mechanical Engineering, School of Engineering, Cochin University of Science and Technology, Ernakulam 682022, India

Article ID: 4043
Keywords: diffusion absorption refrigeration; isobutane; dimethylformamide; helium; coefficient of performance; cooling capacity; mass flow rate; exergy analysis

Abstract

Diffusion absorption refrigeration (DAR) is a promising cycle concerning renewable energy utilization, as the cycle can operate using only thermal energy input.  However, to realize the benefits of the DAR cycle, there is a need to develop an improved understanding of how design parameters influence its performance. The cycle’s performance was particularly sensitive to several factors: the rate of heat added and the temperature of the generator, the effectiveness of the gas and solution heat exchangers, the mass flow rate of the refrigerant, and the type of working fluid. The aim of this research work is to conduct numerical simulations of the diffusion absorption refrigeration (DAR) cycle to study the thermodynamic performances. The working fluids utilized in this system are isobutane (R600a) (C4H10) as a refrigerant, dimethylformamide (CH3)2NC(O)H, as absorbent and helium as the inert gas. The cycle operation characteristics are investigated through numerical analysis, in terms of the coefficient of performance (COP) and minimum temperature by using the effect of generator temperature, absorber temperature, evaporator temperature and the solution concentrations. The performance of the system is examined by computer simulation using MATLAB software. The mathematical model will provide a reasonable estimation of the maximum COP, cooling capacity, mass flow rate, and exergy analysis. The refrigeration cycle experiments were conducted under the ambient condition of 30 ℃. Based on a mathematical model, performance evaluation and exergy analysis of the system are performed. The experiment set included a 0.04 m3 volume of commercial absorption diffusion refrigerator working with the dimethylformamide (CH3)2NC(O)H solution. Furthermore, the results obtained in the proposed system compare with the previous studies.

Published
2026-03-12
How to Cite
Valiyandi, S., & Thampi, G. (2026). Thermodynamic investigation of a diffusion absorption refrigeration system with an isobutane–dimethylformamide–helium working fluid blend. Energy Storage and Conversion, 4(1). https://doi.org/10.59400/esc4043
Section
Article

References

[1]Pavanello F, De Cian E, Davide M, et al. Air-conditioning and the adaptation cooling deficit in emerging economies. Nature Communications. 2021; 12(1): 6460. doi: 10.1038/s41467-021-26592-2

[2]Wang H, Zhao L, Cao R, et al. Refrigerant alternative and optimization under the constraint of the greenhouse gas emissions reduction target. Journal of Cleaner Production. 2021; 296: 126580. doi: 10.1016/j.jclepro.2021.126580

[3]Bolaji BO. Theoretical assessment of new low global warming potential refrigerant mixtures as eco-friendly alternatives in domestic refrigeration systems. Scientific African. 2020; 10: e00632. doi: 10.1016/j.sciaf.2020.e00632

[4]Khelifa S, Ramadan K, Ammar MAH, et al. Performance evaluation of an absorption refrigeration system using R1234yf-organic absorbents working fluids. Science and Technology for the Built Environment. 2021; 27(7): 936–947. doi: 10.1080/23744731.2021.1913380

[5]Lima AAS, Leite GdNP, Ochoa AAV, et al. Absorption refrigeration systems based on ammonia as refrigerant using different absorbents: Review and applications. Energies. 2020; 14(1): 48. doi: 10.3390/en14010048

[6]Al-Falahi A, Alobaid F, Epple B. Thermo-economic comparisons of environmentally friendly solar assisted absorption air conditioning systems. Applied Sciences. 2021; 11(5): 2442. doi: 10.3390/app11052442

[7]Abedin R, Shen Y, Flake JC, et al. Deep eutectic solvents mixed with fluorinated refrigerants for absorption refrigeration: A molecular simulation study. The Journal of Physical Chemistry B. 2020; 124(22): 4536–4550. doi: 10.1021/acs.jpcb.0c01860

[8]Gardenghi ÁR, Lacerda JF, Tibiriçá CB, et al. Numerical and experimental study of the transient behavior of a domestic vapour compression refrigeration system—Influence of refrigerant charge and ambient temperature. Applied Thermal Engineering. 2021; 190: 116728. doi: 10.1016/j.applthermaleng.2021.116728

[9]Kong D, Yin X, Ding X, et al. Global optimization of a vapour compression refrigeration system with a self-adaptive differential evolution algorithm. Applied Thermal Engineering. 2021; 197: 117427. doi: 10.1016/j.applthermaleng.2021.117427

[10]Najjaran A, Freeman J, Ramos A, et al. Experimental investigation of an ammonia-water-hydrogen diffusion absorption refrigerator. Applied Energy. 2019; 256: 113899. doi: 10.1016/j.apenergy.2019.113899

[11]Srikhirin P, Aphornratana S. Investigation of a diffusion absorption refrigerator. Applied Thermal Engineering. 2002; 22(11): 1181–1193. doi: 10.1016/S1359-4311(02)00049-2

[12]Zhang B, Chen W, Sun Q, et al. Numerical Evaluation of Thermal Performances of Diffusion–Absorption Refrigeration Using 1,3-Dimethylimidazolylium Dimethylphosphate/Methanol/Helium as Working Fluid. Energy Conversion and Management. 2017; 152: 201–213. doi: 10.1016/j.enconman.2017.09.048

[13]Gurevich B, Zohar A. Analytical model for the prediction of performance of a solar driven diffusion absorption cooling system. International Journal of Thermodynamics. 2021; 24(4): 42–48. doi: 10.5541/ijot.929863

[14]Wankhede SV, Hole JA, Patil BL. Performance of tetrafluoroethane (R134a)-dimethyl formamide diffusion absorption air cooling system with variable power input. International Journal of Ambient Energy. 2020; 43(1): 2019–2025. doi: 10.1080/01430750.2020.1722225

[15]Wang Q, Liu YL, Wang SK, et al. Experiments on the performance of bubble pumps with R134a/R23-DMF solutions for diffusion absorption refrigerator. Applied Thermal Engineering. 2020; 177: 115481. doi: 10.1016/j.applthermaleng.2020.115481

[16]Zohar A, Jelinek M, Levy A, et al. Performance of diffusion absorption refrigeration cycle with organic working fluids. International Journal of Refrigeration. 2009; 32(6): 1241–1246. doi: 10.1016/j.ijrefrig.2009.01.010

[17]Adjibade MIS, Thiam A, Awanto C, et al. Dynamic investigation of the diffusion absorption refrigeration system NH3-H2O-H2. Case Studies in Thermal Engineering. 2017; 10: 468–474. doi: 10.1016/j.csite.2017.10.006

[18]Elsayed M, Attia A, Tawfeek S. Steady state numerical simulation and studying performance of a modified diffusion absorption refrigeration cycle. Alexandria Engineering Journal. 2022; 61(4): 2591–2600. doi: 10.1016/j.aej.2021.07.027

[19]Valiyandi S, Thampi G. Forecasting the performance of a diffusion absorption refrigeration system using optimal fluid blend—A neural network approach. Environmental Progress & Sustainable Energy. 2022; 41: e13890. doi: 10.1002/ep.13890

[20]Lee G, Choi HW, Kang YT. Cycle performance analysis and experimental validation of a novel diffusion absorption refrigeration system using R600a/n-octane. Energy. 2021; 217: 119328. doi: 10.1016/j.energy.2020.119328

[21]Sözen A, Keçebaş A, Gürbüz EY. Enhancing the thermal performance of diffusion absorption refrigeration system by using magnesium aluminate spinel oxide compound nanoparticles: An experimental investigation. Heat and Mass Transfer. 2021; 57: 1583–1592. doi: 10.1007/s00231-021-03046-5

[22]Senthilkumar A, Anderson A, Sekar M. Performance analysis of R600a vapour compression refrigeration system using CuO/Al2O3 hybrid nano lubricants. Applied Nanoscience. 2021; 13: 899–915. doi: 10.1007/s13204-021-01936-y

[23]Çetiner C. Thermal analysis of operating a solar-powered diffusion absorption refrigerator with a parabolic collector. Case Studies in Thermal Engineering. 2024; 53: 103893. doi: 10.1016/j.csite.2023.103893

[24]Garma R, Ben-Ezzine N, Bellagi A. Experimental and numerical investigation on diffusion-absorption refrigeration system using low GWP refrigerant R600, C9H20 and helium. International Journal of Thermofluids. 2025; 27: 101246. doi: 10.1016/j.ijft.2025.101246

[25]Valiyandi S, Thampi G. Solution concentration influence on the performance of a diffusion absorption refrigeration system using different refrigerant blend. Journal of Scientific Research. 2025; 17(2): 457–470. doi: 10.3329/jsr.v17i2.75859

[26]Harraz AA, Haslam AJ, Mac Dowell N, et al. Computer-aided molecular design of diffusion–absorption refrigeration modules for low-temperature solar collectors. Energy Conversion and Management. 2025; 343: 120067. doi: 10.1016/j.enconman.2025.120067

[27]Gurevich B. Performance analysis of diffusion–absorption refrigerator operating with MgAl2O4 nanoparticles and R1234yf–DMAC. International Journal of Refrigeration. 2026; 185: 54–61. doi: 10.1016/j.ijrefrig.2026.02.009

[28]Zebbar S, Zebbar D, Rahmani Z. CFD analysis of an evaporator in diffusion absorption refrigeration systems using helium as an auxiliary gas. International Journal of Refrigeration. 2026; 183: 95–107. doi: 10.1016/j.ijrefrig.2026.01.003

[29]Ersöz MA. Investigation the effects of different heat inputs supplied to the generator on the energy performance in diffusion absorption refrigeration systems. International Journal of Refrigeration. 2015; 54: 10–21. doi: 10.1016/j.ijrefrig.2015.02.013