Nitrided copper-iron composite oxides derived from layered double hydroxides for enhanced carbon dioxide electroreduction to methane and formic acid

  • Dian Song State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Jinqing He State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Yiping Wang State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China; Quzhou Institute for Innovation in Resource Chemical Engineering, Quzhou 324000, Zhejiang Province, China
  • Xuhui Zhao State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Fazhi Zhang State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Xiaodong Lei State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China; Quzhou Institute for Innovation in Resource Chemical Engineering, Quzhou 324000, Zhejiang Province, China
Ariticle ID: 369
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Keywords: Nitrided copper-iron composite oxides derived from layered double hydroxides for enhanced carbon dioxide electroreduction to methane and formic acid

Abstract

The reduction of carbon dioxide into valuable chemical products is a promising solution to address carbon balance and energy issues. Herein, amorphous nitrided copper-iron oxides are prepared by gas-phase nitriding of CuFe-layered double hydroxide precursors with urea as a nitrogen source. The obtained materials show high activity for CO2 electroreduction to methane and formic acid, achieving a total Faraday efficiency of 74.7% at −0.7 V vs. RHE and exhibiting continuous 10 h durability in the H-cell. The uniformly distributed Cu+ sites act as active sites by losing electrons to activate CO2. During the CO2 electroreduction, CO2 is converted to *COOH via proton-electron coupling; *COOH combines directly with a proton in solution to produce the HCOOH product; and the other part of *COOH undergoes a protonated dehydration process to form the *CHO intermediate, which dehydrates again to form CH4. This study provides a new approach for designing CO2 electroreduction catalysts.

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Published
2024-05-08
How to Cite
Song, D., He, J., Wang, Y., Zhao, X., Zhang, F., & Lei, X. (2024). Nitrided copper-iron composite oxides derived from layered double hydroxides for enhanced carbon dioxide electroreduction to methane and formic acid. Energy Storage and Conversion, 2(2), 369. https://doi.org/10.59400/esc.v2i2.369
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