Electrochemical performance of Pr0.6Sr0.4Fe0.8Co0.2O3−δ as potential cathode material for IT-SOFC
Abstract
Solid oxide fuel cells (SOFCs) are renowned for being effective energy sources that have potential to influence how energy is developed in future. SOFCs operate at low temperatures provides different benefits for widespread commercialization. In the present study a perovskite material Pr0.6Sr0.4Fe0.8Co0.2O3−δ (PSFCo) was investigated as cathode for SOFC in intermediate temperature range. Glycine nitrate process was used for the preparation of the samples. PSFCo exhibited cubic structure having small particle size (100–200 nm). The electrical conductivity of the PSFCo was measured as function of temperature up to 850 ℃. The sample displayed maximum electrical conductivity of 370 Scm−1 at around 550–600 ℃. The polarization behavior of PSFCo was calculated by means of AC impedance with Sm0.8Ce0.2O2 (SDC) as electrolyte. The value of area specific resistance (ASR) was calculated as 0.146 Ωcm2 at 800 ℃ and 0.248 Ωcm2 at 700 ℃.
References
[1]Richter J, Holtappels P, Graule T, et al. Materials design for perovskite SOFC cathodes. Monatshefte für Chemie—Chemical Monthly. 2009; 140(9): 985-999. doi: 10.1007/s00706-009-0153-3
[2]Choudhury R, Das UJ, Ceruti A, et al. Visco-elastic effects on the three dimensional hydrodynamic flow past a vertical porous plate. Int. Inf. Eng. Technol. Assoc. 2013; 31: 1-8.
[3]Ashrafi H, Pourmahmoud N, Mirzaee I, et al. Performance improvement of proton-exchange membrane fuel cells through different gas injection channel geometries. International Journal of Energy Research. 2022; 46(7): 8781-8792. doi: 10.1002/er.7755
[4]Gao Y, Zhang M, Fu M, et al. A comprehensive review of recent progresses in cathode materials for Proton-conducting SOFCs. Energy Reviews. 2023; 2(3): 100038. doi: 10.1016/j.enrev.2023.100038
[5]Cigolotti V, Genovese M, Fragiacomo P. Comprehensive Review on Fuel Cell Technology for Stationary Applications as Sustainable and Efficient Poly-Generation Energy Systems. Energies. 2021; 14(16): 4963. doi: 10.3390/en14164963
[6]Li H, Wang Y, Liu H, et al. Interaction between SOFCs interconnect Cr-free multicomponent spinel coating materials and chromia. International Journal of Hydrogen Energy. 2023; 48(81): 31700-31707. doi: 10.1016/j.ijhydene.2023.04.324
[7]Colomer MT, Steele BCH, Kilner JA. Structural and electrochemical properties of the Sr0.8Ce0.1Fe0.7Co0.3O3−δ perovskite as cathode material for ITSOFCs. Solid State Ionics. 2002; 147(1-2): 41-48.
[8]Ran R, Wu X, Quan C, et al. Effect of strontium and cerium doping on the structural and catalytic properties of PrMnO oxides. Solid State Ionics. 2005; 176(9-10): 965-971. doi: 10.1016/j.ssi.2004.11.018
[9]Riza F, Ftikos C, Tietz F, Fischer W. Preparation and Characterization of Ln0.8Sr0.2Fe0.8Co0.2O3−x(Ln= La, Pr, Nd, Sm, Eu, Gd). Journal of the European Ceramic Society. 2001; 21: 1769-1773.
[10]Qiu L, Ichikawa T, Hirano A, et al. Ln1−xSrxCo1−yFeyO3−δ (Ln = Pr, Nd, Gd; x = 0.2, 0.3) for the electrodes of solid oxide fuel cells. Solid State Ionics. 2003; 158: 55-65.
[11]Ishihara T, Kudo T, Matsuda H, et al. Doped PrMnO3 Perovskite Oxide as a New Cathode of Solid Oxide Fuel Cells for Low Temperature Operation. Journal of The Electrochemical Society. 1995; 142(5): 1519-1524. doi: 10.1149/1.2048606
[12]Ishihara T, Honda M, Shibayama T, et al. Intermediate Temperature Solid Oxide Fuel Cells Using a New LaGaO3 Based Oxide Ion Conductor: I. Doped as a New Cathode Material. Journal of The Electrochemical Society. 1998; 145(9): 3177-3183. doi: 10.1149/1.1838783
[13]Kostogloudis GC, Vasilakos N, Ftikos C. Crystal structure, thermal and electrical properties of Pr1−xSrxCoO3−δ (x = 0, 0.15, 0.3, 0.4, 0.5) perovskite oxides. Solid State Ionics. 1998; 106: 207-218.
[14]Steele BC, Bae JM. Properties of La0.6Sr0.4Co0.2Fe0.8O3−x (LSCF) double layer cathodes on gadolinium-doped cerium oxide (CGO) electrolytes: II. Role of oxygen exchange and diffusion. Solid State Ionics. 1998; 106: 255-261.
[15]Xia C, Rauch W, Chen F, Liu M. Sm0.5Sr0.5CoO3 cathodes for low-temperature SOFCs. Solid State Ionics. 2002; 149: 11-19.
[16]Al Daroukh M, Vashook V, Ullmann H, et al. Oxides of the AMO3 and A2MO4-type: structural stability, electrical conductivity and thermal expansion. Solid State Ionics. 2003; 158: 141-150.
[17]Wang Y, Wang S, Wang Z, et al. Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ-CGO-Ag cathode for IT-SOFCs. Journal of Alloys and Compounds. 2007; 428(1-2): 286-289. doi: 10.1016/j.jallcom.2006.02.071
[18]Chen W, Wen T, Nie H, Zheng R. Study of Ln0.6Sr0.4Co0.8Mn0.2O3-δ (Ln = La, Gd, Sm or Nd) as the cathode materials for intermediate temperature SOFC. Materials research bulletin. 2003; 38: 1319-1328.
[19]Rossignol C, Ralph J, Bae JM, Vaughey J. Ln1−xSrxCoO3 (Ln = Gd, Pr) as a cathode for intermediate-temperature solid oxide fuel cells. Solid State Ionics. 2004; 175: 59-61.
[20]Kim JH, Baek SW, Lee C, et al. Performance analysis of cobalt-based cathode materials for solid oxide fuel cell. Solid State Ionics. 2008; 179(27-32): 1490-1496. doi: 10.1016/j.ssi.2008.01.086
[21]Tai LW, Nasrallah M, Anderson H, et al. Structure and electrical properties of La1−xSrxCo1−yFeyO3. Part 1. The system La0.8Sr0.2Co1−yFeyO3. Solid State Ionics. 1995; 76: 259-271.
[22]Chen X, Wu N, Ignatiev A. Structure and conducting properties of La1-xSrxCoO3-δ films. Journal of the European Ceramic Society. 1999; 19: 819-822. doi: 10.1016/S0955-2219(98)00323-9
[23]Chen X, Wu NJ, Smith L, et al. Thin-film heterostructure solid oxide fuel cells. Applied Physics Letters. 2004; 84(14): 2700-2702. doi: 10.1063/1.1697623
[24]Pederson LR, Singh P, Zhou XD. Application of vacuum deposition methods to solid oxide fuel cells. Vacuum. 2006; 80(10): 1066-1083. doi: 10.1016/j.vacuum.2006.01.072
[25]Zamani F, Taghvaei AH. Characterization and magnetic properties of nanocrystalline Mg1-CdFe2O4 (x= 0.0–0.8) ferrites synthesized by glycine-nitrate autocombustion method. Ceramics International. 2018; 44(14): 17209-17217. doi: 10.1016/j.ceramint.2018.06.178
[26]Piao J, Sun K, Zhang N, et al. Preparation and characterization of Pr1−xSrxFeO3 cathode material for intermediate temperature solid oxide fuel cells. Journal of Power Sources. 2007; 172(2): 633-640. doi: 10.1016/j.jpowsour.2007.05.023
[27]Gou Y, Li G, Ren R, et al. Pr-Doping Motivating the Phase Transformation of the BaFeO3-δ Perovskite as a High-Performance Solid Oxide Fuel Cell Cathode. ACS Applied Materials & Interfaces. 2021; 13(17): 20174-20184. doi: 10.1021/acsami.1c03514
[28]Steele BC. Survey of materials selection for ceramic fuel cells II. Cathodes and anodes. Solid State Ionics. 1996; 86: 1223-1234.
[29]Aysal HE, Kılıç F, Çakmak G, et al. Thermal plasma synthesis of (La,Sr)CoO3-(La,Sr)2CoO4 composite cathodes for intermediate temperature solid oxide fuel cells (IT-SOFC). International Journal of Hydrogen Energy. 2024; 51: 1477-1486. doi: 10.1016/j.ijhydene.2023.07.031
Copyright (c) 2024 M. Shamshi Hassan
This work is licensed under a Creative Commons Attribution 4.0 International License.