Microwave absorption properties and mechanism of novel apatite-type materials Mn₂Gd₇.₅Ce₀.₅(SiO₄)₆O₂

  • Haikun Liu National Center of Technology Innovation for Display, Guangdong Juhua Research Institute of Advanced Display, Guangzhou 510525, China
  • Xiaoming Liu National Center of Technology Innovation for Display, Guangdong Juhua Research Institute of Advanced Display, Guangzhou 510525, China
  • Ning Liu School of Science, China University of Geosciences, Beijing 100083, China; School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
  • Lefu Mei School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Ariticle ID: 1630
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Keywords: apatite structure; Mn₂Gd₇.₅Ce₀.₅(SiO₄)₆O₂; microwave absorption performance

Abstract

Manganese minerals possess a high intrinsic magnetic moment, making them excellent materials for microwave absorption. Rare earth elements, with their unique electronic structures and interactions between spin electrons and orbitals, can further enhance the performance of absorbing materials. In this study, we designed a novel microwave absorbing material by incorporating manganese into an apatite structure with adjustable chemical composition. The material Mn₂Gd₇.₅Ce₀.₅(SiO₄)₆O₂, exhibiting specific microwave absorption properties, was synthesized using a high-temperature solid-phase method. The results indicate that at a sample thickness of 5 mm, the absorption frequency bandwidth below −10 dB within the 2–12 GHz range reaches 1.2 GHz, with a peak absorption of −21.78 dB. Additionally, smaller particles were prepared using the sol-gel method, achieving a peak absorption of −39.75 dB. The primary absorption mechanism for both particle types is attributed to magnetic loss. This work presents a new approach to designing microwave absorbing materials and significantly contributes to expanding the range of apatite-type materials.

References

[1] Lan D, Li H, Wang M, et al. Recent advances in construction strategies and multifunctional properties of flexible electromagnetic wave absorbing materials. Materials Research Bulletin. 2023; 112630.

[2] Wang D, Jin J, Guo Y, et al. Lightweight waterproof magnetic carbon foam for multifunctional electromagnetic wave absorbing material. Carbon. 2023; 202: 464–474.

[3] Hu J, Liu S, Wang Y, et al. Manganese phosphate coated flaky FeSiAl powders with enhanced microwave absorbing properties and improved corrosion resistance. Materials Chemistry and Physics. 2023; 296: 127274.

[4] Yang Z, Yu Z, Xu Z, et al. Molten salt-directed synthesis of carbon nanotube/C3N4/manganese carbodiimide (MnNCN): Novel microwave absorbing materials. Materials Research Bulletin. 2024; 175: 112757.

[5] Jin L, Chen J, Zhang L, et al. Coupling dielectric and magnetic components on a ternary composite for enhancing impedance matching and microwave absorption. Ceramics International. 2024.

[6] Vinnik DA, Gudkova SA, Zhivulin VE, et al. Ferrite-based solid solutions: structure types, preparation, properties, and potential applications. Inorganic Materials. 2021; 57: 1109–1118.

[7] Deng Y, Wang L, Liu W, et al. Research Progress on Controllable Absorption Properties of Rare Earth Element Doped Electromagnetic Wave Absorbing Materials. Chinese Journal of Chemistry. 2024.

[8] Chen Z, Li Z, Chen J, et al. Recent advances in selective separation technologies of rare earth elements: A review. Journal of Environmental Chemical Engineering. 2022; 10(1): 107104.

[9] Guo J, Jing Y, Shen T, et al. Effect of doped strontium on catalytic properties of La1‒xSrxMnO3 for rhodamine B degradation. Journal of Rare Earths. 2021; 39(11): 1362–1369.

[10] Munazat DR, Kurniawan B, Kurita N, et al. Investigation of the impact of A-site cation disorder on the structure, magnetic properties, and magnetic entropy change of trisubstituted divalent ions in La0.7(Ba, Ca, Sr)0.3MnO3 manganite. Physical Chemistry Chemical Physics. 2024; 26(26): 18343–18367.

[11] Liu H, Liao L, Pan X, et al. Recent research progress of luminescent materials with apatite structure: a review. Open Ceramics. 2022; 10: 100251.

[12] Jing XD, Li ZG, Chen ZT, et al. Effect of praseodymium valence change on the structure, magnetic, and microwave absorbing properties of M-type strontium ferrite: the mechanism of influence of citric acid dosage and calcination temperature. Materials Today Chemistry. 2023; 30: 101537.

[13] Khanvilkar MB, Nikumbh AK, Pawar RA, et al. Effect of divalent/trivalent doping on structural, electrical and magnetic properties of spinel ferrite nanoparticles. Engineered Science. 2023; 22: 850.

[14] Fu J, Liu N, Mei L, et al. Synthesis of Ce-doped Mn3Gd7−xCex(SiO4)6O1. 5 for the enhanced catalytic ozonation of tetracycline. Scientific Reports. 2019; 9(1): 18734.

[15] Gupta I, Singh D, Singh S, et al. Study of structural and spectroscopic characteristics of novel color tunable yellowish-white Dy3+ doped Gd4Al2O9 nanophosphors for NUV-based WLEDs. Journal of Molecular Structure. 2023; 1272: 134199.

[16] Tian F, Gao Y, Wang A, et al. Effect of Mn substitution on structural, magnetic and microwave absorption properties of Co2Y hexagonal ferrite. Journal of Magnetism and Magnetic Materials. 2023; 587: 171229.

[17] Yue J, Cheng L, Xiong J, et al. Effect of neodymium doping on structure, magnetic properties and microwave absorption performance of SrMnO3. Journal of Rare Earths. 2024; 42(2): 354–363.

[18] Yin Y, Yan S, Ni Z, et al. Economical synthesized Mn3O4/biomass-derived carbon from vegetable sponge composites and its excellent supercapacitive behavior. Biomass Conversion and Biorefinery. 2023; 13(13): 12115–12124.

[19] Dhandapani P, Nayak PK, Maruthapillai A. Improved electrochemical performance and charge storage mechanism of NiMnCoO4 by XPS study. Materials Chemistry and Physics. 2023; 297: 127287.

[20] Zheng Q, Yu M, Wang W, et al. Enhanced microwave absorption performance of Fe/C nanofibers by adjusting the magnetic particle size using different electrospinning solvents. Ceramics International. 2020; 46(18): 28603–28612.

[21] Quan B, Gu W, Sheng J, et al. From intrinsic dielectric loss to geometry patterns: Dual-principles strategy for ultrabroad band microwave absorption. Nano Research. 2021; 14: 1495–1501.

[22] Lei C, Du Y. Tunable dielectric loss to enhance microwave absorption properties of flakey FeSiAl/ferrite composites. Journal of Alloys and Compounds. 2020; 822: 153674.

[23] Elmahaishi MF, Ismail I, Muhammad FD. A review on electromagnetic microwave absorption properties: their materials and performance. Journal of Materials Research and Technology. 2022; 20: 2188–2220.

[24] Yang SJ, Park KT, Im J, et al. Ultrafast 27 GHz cutoff frequency in vertical WSe2 Schottky diodes with extremely low contact resistance. Nature communications. 2020; 11(1): 1574.

[25] Wang F, Liu Y, Zhao H, et al. Controllable seeding of nitrogen-doped carbon nanotubes on three-dimensional Co/C foam for enhanced dielectric loss and microwave absorption characteristics. Chemical Engineering Journal. 2022; 450: 138160.

Published
2024-11-20
How to Cite
Liu, H., Liu, X., Liu, N., & Mei, L. (2024). Microwave absorption properties and mechanism of novel apatite-type materials Mn₂Gd₇.₅Ce₀.₅(SiO₄)₆O₂. Materials Technology Reports, 2(2), 1630. https://doi.org/10.59400/mtr1630
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