Enhanced medicinal applications of Co-doped Zn0.5Ni0.5Fe2-xO4 for (X = 0.00 and 0.0250) soft ferrites: A structural analysis

  • Abu Zar Muaawia Department of Physics, University of the Punjab, Lahore 54590, Punjab, Pakistan
  • Ali Mujtaba Department of Physics, The University of Lahore, Lahore 53700, Punjab, Pakistan
  • M. I. Khan Department of Physics, The University of Lahore
  • Babar Ali Department of Physics, University of Okara, Okara 56300, Punjab, Pakistan
  • Ansa Karamat Department of Physics, GC Women University Sialkot, Punjab 51310, Pakistan
  • Adnan Asghar School of Quantitative Sciences, UUM College of Arts & Sciences, Universiti Utara Malaysia, UUM Sintok 06010, Kedah Darul Aman, Malaysia
Ariticle ID: 237
95 Views, 17 PDF Downloads
Keywords: ferrites application, medicine, XRD, spinel ferrites, Co-doping

Abstract

In this experimental research paper, we investigate the potential enhancement of Co-doped Zn0.5Ni0.5Fe2-xCoxO4 for (x = 0.0, and 0.0250) ferrites, synthesis by green synthesis method for applications in medicine. The structural analysis of the synthesized material is a crucial step in understanding its suitability for medical applications. X-ray Diffraction (XRD) is employed to elucidate the crystallographic structure of the Co-doped ZnNiFe2O4 ferrites. The results demonstrate that the doping process has a significant influence on the material’s crystal structure, which may impact its potential in various biomedical applications. The Co-doped ZnNiFe2O4 spinel ferrite materials become more suitable for medical applications as the decrease in X-ray density and simultaneous increase in bulk density can facilitate better tissue penetration and biocompatibility, making them ideal for non-invasive medical imaging and therapeutic applications, while minimizing potential health risks.

References

[1] Rethi NR, Murugeswari A, Sankaranarayanan R. Role of Al3+ and Cr3+ Ions on structural, optical, magnetic, and impedance properties of AlyCrxZn(0.4-y)Ni(0.6-x)Fe2O4 nanoparticles. Journal of Superconductivity and Novel Magnetism 2023; 36: 1443–1454. doi: 10.1007/s10948-023-06579-4

[2] Saleem S, Ashiq MN, Manzoor S, et al. Analysis and characterization of opto-electronic properties of iron oxide (Fe2O3) with transition metals (Co, Ni) for the use in the photodetector application. Journal of Materials Research and Technology 2023; 25: 6150–6166. doi: 10.1016/j.jmrt.2023.07.065

[3] Li Y, Shi C, Zhang H, He X, Liu L. Magnetic Properties and Local Structure of the (La, Co) Co-doped Bi1−xLaxFe0.95Co0.05O3. Crystals 2021; 11(9): 1059. doi:10.3390/cryst11091059

[4] Yu X, Zhou N, Liu R, et al. Effect of Zn2+-Sn4+ co-substitution on structural and magnetic properties of SrFe12-2xZnxSnxO19 (x = 0–2) M-type strontium ferrite. Physica B: Condensed Matter 2023; 653: 414676. doi: 10.1016/j.physb.2023.414676

[5] Wan K, Liu W, Ding Y, et al. Comparative investigation of insulation techniques based on APTES for different structures and magnetic properties of soft magnetic composites. Journal of Magnetism and Magnetic Materials 2023; 571: 170571. doi: 10.1016/j.jmmm.2023.170571

[6] Sheikh FA, Gilani ZA, Noor ul Huda Khan Asghar HM, et al. Structural, morphological, and magneto-dielectric features of Ni-Co-Pr ferrites for high density memory and high frequency devices. Journal of Magnetism and Magnetic Materials 2023; 587: 171240. doi: 10.1016/j.jmmm.2023.171240

[7] Ameen F, Majrashi N. Recent trends in the use of cobalt ferrite nanoparticles as an antimicrobial agent for disability infections: A review. Inorganic Chemistry Communications 2023; 156: 111187. doi: 10.1016/j.inoche.2023.111187

[8] Wu X, Ding Z, Song N, et al. Effect of the rare-earth substitution on the structural, magnetic and adsorption properties in cobalt ferrite nanoparticles. Ceramics International 2016; 42(3): 4246–4255. doi: 10.1016/j.ceramint.2015.11.100

[9] Frei EH, Gunders E, Pajewsky M, et al. Ferrites as contrast material for medical X-ray diagnosis. Journal of Applied Physics 1968; 39(2): 999–1001. doi: 10.1063/1.1656366

[10] Tamboli QY, Patange SM, Mohanta YK, et al. Green synthesis of cobalt ferrite nanoparticles: An emerging material for environmental and biomedical applications. Journal of Nanomaterials 2023; 2023: 9770212. doi: 10.1155/2023/9770212

[11] Mujtaba A, Khan MI, Hasan MS, et al. Tailoring the structural, optical, photoluminescence, dielectric and electrical properties of Zn0.6Ni0.2Mg0.2Fe2-xLaxO4 (x= 0.00, 0.0125, 0.0250, 0.0375). Journal of Materials Research and Technology 2023; 23: 4538–4550. doi: 10.1016/j.jmrt.2023.02.038

[12] Wu Z, Zhang Y, Shan L, Han Z. Properties of Sm–Mn substituted M-type strontium ferrites synthesized by the sol-gel method. Ferroelectrics 2023; 614(1): 183–193. doi: 10.1080/00150193.2023.2227081

[13] Latif S, Liaqat A, Imran M, et al. Development of zinc ferrite nanoparticles with enhanced photocatalytic performance for remediation of environmentally toxic pharmaceutical waste diclofenac sodium from wastewater. Environmental Research 2023; 216(Part 2): 114500. doi: 10.1016/j.envres.2022.114500

[14] Hussein MM, Saafan SA, Abosheiasha HF, et al. Crystal structure and peculiarities of microwave parameters of Co1−xNixFe2O4 nano spinel ferrites. RSC Advances 2023; 13(38): 26879–26891. doi: 10.1039/d3ra04557a

[15] Katoch G, Himanshi, Jasrotia R, et al. Crystal structure, synthesis, properties and potential applications of cobalt spinel ferrite: A brief review. Materials Today: Proceedings 2023; in press.

[16] Abdalazeez A, Li T, Liu X, et al. Investigation of BaFe2O4 oxygen carrier modified by supports in chemical looping gasification of biochar. International Journal of Hydrogen Energy 2023; in press.

[17] Nguyena NT, Nguyen VA. Ultrasound-assisted sol-gel synthesis, characterization, and photocatalytic application of ZnO nanoparticles. Digest Journal of Nanomaterials and Biostructures 2023; 18(3): 889–897. doi: 10.15251/DJNB.2023.183.886

[18] Mosleh-Shirazi S, Kasaee SR, Dehghani F, et al. Investigation through the anticancer properties of green synthesized spinel ferrite nanoparticles in present and absent of laser photothermal effect. Ceramics International 2023; 49(7): 11293–11301. doi: 10.1016/j.ceramint.2022.11.329

[19] Udhaya PA, Ahmad A, Meena M, et al. Copper Ferrite nanoparticles synthesised using a novel green synthesis route: Structural development and photocatalytic activity. Journal of Molecular Structure 2023; 1277: 134807. doi: 10.1016/j.molstruc.2022.134807

[20] Godara SK, Prakash J, Jasrotia R, et al. Green synthesis of magnetic nanoparticles of BaFe12O19 hexaferrites using tomato pulp: Structural, morphological, optical, magnetic and dielectric traits. Journal of Materials Science: Materials in Electronics 2023; 34(20): 1516. doi: 10.1007/s10854-023-10859-z

[21] Xing C, Liu CY, Lai C, Zhang SQ. Tuning d-spacing of graphene oxide nanofiltration membrane for effective dye/salt separation. Rare Metals 2023; 42(2): 418–429. doi: 10.1007/s12598-022-02153-4

[22] Thakur A, Verma R, Wan F, et al. Investigation of structural, elastic and magnetic properties of Cu2+ ions substituted cobalt nano ferrites. Journal of Magnetism and Magnetic Materials 2023; 581: 170980. doi: 10.1016/j.jmmm.2023.170980

[23] Arshad M, Khan W, Abushad M, et al. Superior energy storage performance and excellent multiferroic properties in BaTi1-xGdxO3 (0≤ x ≤ 0.06) ceramics. Materials Research Bulletin 2023; 169: 112504. doi: 10.1016/j.materresbull.2023.112504

[24] Khan I, Sadiq I, Ashiq MN, Rana MUD. Role of Ce–Mn substitution on structural, electrical and magnetic properties of W-type strontium hexaferrites. Journal of Alloys and Compounds 2011; 509(31): 8042–8046. doi: 10.1016/j.jallcom.2011.05.013

[25] Vinayak V, Khirade P, Birajdar SD, et al. Low temperature synthesis of magnesium doped cobalt ferrite nanoparticles and their structural properties. International Advanced Research Journal in Science, Engineering and Technology 2015; 2(3): 55–58. doi: 10.17148/IARJSET.2015.2313

[26] Kale SB, Somvanshi SB, Sarnaik MN, et al. Enhancement in surface area and magnetization of CoFe2O4 nanoparticles for targeted drug delivery application. AIP Conference Proceedings 2018; 1953(1). doi: 10.1063/1.5032528

[27] Barkule RS, Kurmude DV, Raut AV, et al. Structural and electrical conductivity studies in nickel ferrite nano-particles. Solid State Phenomena 2014; 209: 177–181. doi: 10.4028/www.scientific.net/SSP.209.177

[28] Kim DH, Zeng H, Ng TC, Brazel CS. T1 and T2 relaxivities of succimer-coated MFe23+O4 (M=Mn2+, Fe2+ and Co2+) inverse spinel ferrites for potential use as phase-contrast agents in medical MRI. Journal of Magnetism and Magnetic Materials 2009; 321(23): 3899–3904. doi: 10.1016/j.jmmm.2009.07.057

[29] Amiri M, Salavati-Niasari M, Akbari A. Magnetic nanocarriers: Evolution of spinel ferrites for medical applications. Advances in Colloid and Interface Science 2019; 265: 29–44. doi: 10.1016/j.cis.2019.01.003

[30] Amiri S, Shokrollahi H. The role of cobalt ferrite magnetic nanoparticles in medical science. Materials Science and Engineering: C 2013; 33(1): 1–8. doi: 10.1016/j.msec.2012.09.003

Published
2023-08-05
How to Cite
Muaawia, A. Z., Mujtaba, A., Khan, M. I., Ali, B., Karamat, A., & Asghar, A. (2023). Enhanced medicinal applications of Co-doped Zn0.5Ni0.5Fe2-xO4 for (X = 0.00 and 0.0250) soft ferrites: A structural analysis. Journal of AppliedMath, 1(2), 237. https://doi.org/10.59400/jam.v1i2.237
Section
Article