Functionalization of insulating substrate and its hybridization with carbon fibers

  • Prashanta Dhoj Adhikari Department of Food and Technology, and Biotechnology, National College (Faculty of Science), Tribhuvan University, Kathmandu, Nepal
Ariticle ID: 412
322 Views, 96 PDF Downloads
Keywords: insulating glass substrate, conducting carbon materials, hybridization, self-assembled monolayer, surface functionalization

Abstract

In this work, surface functionalization of an insulating glass substrate was performed and it was hybridized with conducting carbon fiber materials, carbon coils. Glass substrate was carried out via different chemical treatments, then an amine terminated self-assembled monolayer was introduced on its surface. Carbon coils were also treated with nitric acid. These surface modified carbon coils, glass substrates, and carbon coils immobilized on glass substrates were analyzed through different analytical tools. Finally, hybridization of carbon coils on glass substrates resulted only in functionalized glass (amine terminated) surfaces via chemical bonding, while the un-functionalize glass substrate did not. Thus, such a stable, recognized practice can apply to fabricate simple microarrays to bind carbon materials or biomolecules for further application.

References

[1] Ståhl PL, Salmén F, Vickovic S, et al. Visualization and analysis of gene expression in tissue sections by spatial transcriptomics. Science. 2016, 353(6294): 78-82. doi: 10.1126/science.aaf2403

[2] Hölz K, Pavlic A, Lietard J, et al. Specificity and Efficiency of the Uracil DNA Glycosylase-Mediated Strand Cleavage Surveyed on Large Sequence Libraries. Scientific Reports. 2019, 9(1). doi: 10.1038/s41598-019-54044-x

[3] Schaudy E, Lietard J, Somoza MM. Sequence Preference and Initiator Promiscuity for De Novo DNA Synthesis by Terminal Deoxynucleotidyl Transferase. ACS Synthetic Biology. 2021, 10(7): 1750-1760. doi: 10.1021/acssynbio.1c00142

[4] Lietard J, Ameur D, Damha MJ, et al. High‐Density RNA Microarrays Synthesized In Situ by Photolithography. Angewandte Chemie International Edition. 2018, 57(46): 15257-15261. doi: 10.1002/anie.201806895

[5] Schaudy E, Hölz K, Lietard J, et al. Simple synthesis of massively parallel RNA microarrays via enzymatic conversion from DNA microarrays. Nature Communications. 2022, 13(1). doi: 10.1038/s41467-022-31370-9

[6] Das A, Santhosh S, Giridhar M, et al. Dipodal Silanes Greatly Stabilize Glass Surface Functionalization for DNA Microarray Synthesis and High-Throughput Biological Assays. Analytical Chemistry. 2023, 95(41): 15384-15393. doi: 10.1021/acs.analchem.3c03399

[7] Dresselhaus MS, Dresselhaus G, Avouris P. Introduction to carbon materials research. Springer Verlag; 2001.

[8] Geim AK, Novoselov KS. The rise of graphene. Nature Materials. 2007, 6(3): 183-191. doi: 10.1038/nmat1849

[9] Lee C, Wei X, Kysar JW, et al. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene. Science. 2008, 321(5887): 385-388. doi: 10.1126/science.1157996

[10] Adhikari PD, Ujihara M, Imae T, et al. Reinforcement on Properties of Poly(vinyl alcohol) Films by Embedding Functionalized Carbon Micro Coils. Journal of Nanoscience and Nanotechnology. 2011, 11(2): 1004-1012. doi: 10.1166/jnn.2011.3057

[11] Adhikari PD, Jeon S, Cha MJ, et al. Immobilization of carbon nanotubes on functionalized graphene film grown by chemical vapor deposition and characterization of the hybrid material. Science and Technology of Advanced Materials. 2014, 15(1): 015007. doi: 10.1088/1468-6996/15/1/015007

[12] Adhikari PD, Ko Y hun, Jung D, et al. Single-wall carbon nanotube hybridized graphene films: self assembly and electrical properties. New Carbon Materials. 2015, 30(4): 342-348. doi: 10.1016/s1872-5805(15)60193-7

[13] Yang S, Chen X, Motojima S. Morphology of the growth tip of carbon microcoils/nanocoils. Diamond and Related Materials. 2004, 13(11-12): 2152-2155. doi: 10.1016/j.diamond.2004.06.014

[14] Motojima S, Chen X. Preparation and Characterization of Carbon Microcoils (CMCs). Bulletin of the Chemical Society of Japan. 2007, 80(3): 449-455. doi: 10.1246/bcsj.80.449

[15] Motojima S, Chen X, Yang S, et al. Properties and potential applications of carbon microcoils/nanocoils. Diamond and Related Materials. 2004, 13(11-12): 1989-1992. doi: 10.1016/j.diamond.2004.06.020

[16] Adhikari PD, Tai Y, Ujihara M, et al. Surface Functionalization of Carbon Micro Coils and Their Selective Immobilization on Surface-Modified Silicon Substrates. Journal of Nanoscience and Nanotechnology. 2010, 10(2): 833-839. doi: 10.1166/jnn.2010.1886

[17] Adhikari PD, Imae T, Motojima S. Selective immobilization of carbon micro coils on patterned substrates and their electrochemical behavior on ITO substrate. Chemical Engineering Journal. 2011, 174(2-3): 693-698. doi: 10.1016/j.cej.2011.09.058

[18] Adhikari PD, Cho J, Park CY. Easy Synthesis of Nitrogen Doped Single-Walled Carbon Nanotubes via Supporting Layer as a Precursor. Materials Focus. 2014, 3(4): 281-285. doi: 10.1166/mat.2014.1180

[19] Adhikari PD, Kim S, Lee S, et al. Immobilization of Iron Oxide Nanoclusters on Surface Functionalized Silicon Substrate and Their Catalytic Behavior to Synthesize Multi-Walled Carbon Nanotubes. Journal of Nanoscience and Nanotechnology. 2013, 13(7): 4587-4592. doi: 10.1166/jnn.2013.7114

[20] Adhikari PD, Song W, Cha MJ, et al. Synthesis of high quality single-walled carbon nanotubes via a catalytic layer reinforced by self-assembled monolayers. Thin Solid Films. 2013, 545: 50-55. doi: 10.1016/j.tsf.2013.07.030

Published
2024-02-22
How to Cite
Adhikari, P. D. (2024). Functionalization of insulating substrate and its hybridization with carbon fibers. Nano Carbons, 2(1). https://doi.org/10.59400/n-c.v2i1.412
Section
Article