Resistance of HVOF-Sprayed Cr3C2-25NiCr and WC-10CO-4Cr coatings to cavitation and erosion by mud jetting
Abstract
This study investigates chromium carbide-based coating material’s cavitation and erosion resistance with 25% nickel-chromium. (Cr3C2-25NiCr) and tungsten carbide coating with 10% cobalt and 4% chromium (WC-10CO-4Cr) coatings deposited by high-velocity oxygen fuel (HVOF) thermal spraying. The coatings were characterized by microstructure, porosity, hardness, and fracture toughness. Cavitation tests were performed in distilled water and water-sand mixtures to assess the synergistic effect of erosion and cavitation. Erosion tests were conducted using a mud jet at different impact angles (30°, 60°, 90°). The Cr3C2-25NiCr coating exhibited higher cavitation resistance due to its higher fracture toughness and lower porosity. However, the WC-10CO-4Cr coating showed superior erosion resistance, attributed to its finer and more homogeneously distributed carbides. The dominant wear mechanisms were micro grooving, carbide detachment, and cracking. The impact angle significantly influenced the erosion rates, with ductile materials like CA6NM steel being more susceptible at lower angles, while brittle coatings showed the opposite behavior. The findings highlight the importance of coating properties and test conditions on the wear performance, providing valuable insights for selecting suitable coatings for hydropower applications.
References
[1]Amarendra HJ, Prathap MS, Karthik S, et al. Combined Slurry and Cavitation Erosion Resistance of Hvof Thermal Spray Coated Stainless Steel. Materials Today: Proceedings. 2017; 4(2): 465-470. doi: 10.1016/j.matpr.2017.01.046
[2]Ding X, Cheng X, Yu X, et al. Structure and cavitation erosion behavior of HVOF sprayed multi-dimensional WC-10Co4Cr coating. Transactions of Nonferrous Metals Society of China. 2018; 28(3): 487-494. doi: 10.1016/S1003-6326(18)64681-3
[3]Ding X, Huang Y, Yuan C, et al. Deposition and cavitation erosion behavior of multimodal WC-10Co4Cr coatings sprayed by HVOF. Surface and Coatings Technology. 2020; 392: 125757. doi: 10.1016/j.surfcoat.2020.125757
[4]Ding Z, Chen W, Wang Q. Resistance of cavitation erosion of multimodal WC-12Co coatings sprayed by HVOF. Transactions of Nonferrous Metals Society of China. 2011; 21(10): 2231-2236. doi: 10.1016/S1003-6326(11)61000-5
[5]Hong S, Mei D, Wu J, et al. Hydro-abrasive erosion and cavitation-silt erosion characteristics of HVOF sprayed WC-Ni cermet coatings under different flow velocities and sand concentrations. Ceramics International. 2023; 49(1): 74–83. doi: 10.1016/j.ceramint.2022.08.282
[6]Hong S, Shi X, Lin J, et al. Microstructure and cavitation-silt erosion behavior of two HVOF-sprayed hardfacing coatings for hydro-turbine applications. Alexandria Engineering Journal. 2023; 69: 483-496. doi: 10.1016/j.aej.2023.02.010
[7]Hong S, Wei Z, Lin J, et al. Cavitation-silt erosion behavior and mechanism in simulated sea water slurries of cermet coatings manufactured by HVOF spraying. Ceramics International. 2023; 49(9): 14355-14366. doi: 10.1016/j.ceramint.2023.01.024
[8]Jonda E, Szala M, Sroka M, et al. Investigations of cavitation erosion and wear resistance of cermet coatings manufactured by HVOF spraying. Applied Surface Science. 2023; 608: 155071. doi: 10.1016/j.apsusc.2022.155071
[9]Kanno A, Takagi K, Arai M. Influence of chemical composition, grain size, and spray condition on cavitation erosion resistance of high-velocity oxygen fuel thermal-sprayed WC cermet coatings. Surface and Coatings Technology. 2020; 394: 125881. doi: 10.1016/j.surfcoat.2020.125881
[10]Kumar H, Chittosiya C, Shukla VN. HVOF Sprayed WC Based Cermet Coating for Mitigation of Cavitation, Erosion & Abrasion in Hydro Turbine Blade. Materials Today: Proceedings. 2018; 5(2): 6413-6420. doi: 10.1016/j.matpr.2017.12.253
[11]Kumar V, Singh V, Verma R, et al. Cavitation-corrosion analysis of HVOF-sprayed WC-Co-Cr-graphene nanoplatelets coatings with LST pre-treatment. International Journal of Refractory Metals and Hard Materials. 2024; 120: 106610. doi: 10.1016/j.ijrmhm.2024.106610
[12]Lamana MS, Pukasiewicz AGM, Sampath S. Influence of cobalt content and HVOF deposition process on the cavitation erosion resistance of WC-Co coatings. Wear. 2018; 398-399: 209-219. doi: 10.1016/j.wear.2017.12.009
[13]Lekatou AG, Sioulas D, Grimanelis D. Corrosion and wear of coatings fabricated by HVOF- spraying of nanostructured and conventional WC–10Co-4Cr powders on Al7075-T6. International Journal of Refractory Metals and Hard Materials. 2023; 112: 106164. doi: 10.1016/j.ijrmhm.2023.106164
[14]Lin J, Hong S, Zheng Y, et al. Cavitation erosion resistance in NaCl medium of HVOF sprayed WC-based cermet coatings at various flow velocities: A comparative study on the effect of Ni and CoCr binder phases. International Journal of Refractory Metals and Hard Materials. 2021; 94: 105407. doi: 10.1016/j.ijrmhm.2020.105407
[15]Maekai IA, Harmain GA, Din ZU, et al. Resistance to Slurry Erosion by Wc-10co-4cr and Cr3C2-25(Ni20cr) Coatings Deposited by Hvof Stainless Steel F6nm. International Journal of Refractory Metals and Hard Materials. 2022; 105: 105830. doi: 10.1016/j.ijrmhm.2022.105830
[16]Pattnayak A, Gupta A, Abhijith NV, et al. Development of rGO doped alumina-based wear and corrosion resistant ceramic coatings on steel using HVOF thermal spray. Ceramics International. 2023; 49(11): 17577-17591. doi: 10.1016/j.ceramint.2023.02.124
[17]Ribu DC, Rajesh R, Thirumalaikumarasamy D, et al. Experimental investigation of erosion corrosion performance and slurry erosion mechanism of HVOF sprayed WC-10Co coatings using design of experiment approach. Journal of Materials Research and Technology. 2022; 18: 293-314. doi: 10.1016/j.jmrt.2022.01.134
[18]Ribu DC, Rajesh R, Thirumalaikumarasamy D, et al. Influence of rotational speed, angle of impingement, concentration of slurry and exposure time on erosion performance of HVOF sprayed cermet coatings on 35CrMo steel. Materials Today: Proceedings. 2021; 46: 7518-7530. doi: 10.1016/j.matpr.2021.01.307
[19]Shi X, Cui D, Wei Z, et al. The influence of sulphide on the ultrasonic cavitation erosion-corrosion behaviors of HVOF-sprayed WC-Cr3C2-Ni coating. Ultrasonics Sonochemistry. 2023; 100: 106629. doi: 10.1016/j.ultsonch.2023.106629
[20]Singh NK, Ang ASM, Mahajan DK, Singh H. Cavitation erosion resistant nickel-based cermet coatings for monel K-500. Tribology International. 2021; 159: 106954. doi: 10.1016/j.triboint.2021.106954
[21]Singh NK, Vinay G, Ang ASM, et al. Cavitation erosion mechanisms of HVOF-sprayed Ni-based cermet coatings in 3.5% NaCl environment. Surface and Coatings Technology. 2022; 434: 128194. doi: 10.1016/j.surfcoat.2022.128194
[22]Singh V, Singh I, Bansal A, et al. Cavitation erosion behavior of high velocity oxy fuel (HVOF) sprayed (VC + CuNi-Cr) based novel coatings on SS316 steel. Surface and Coatings Technology. 2022; 432: 128052. doi: 10.1016/j.surfcoat.2021.128052
[23]Vaz RF, Silveira LL, Cruz JR, et al. Cavitation resistance of FeMnCrSi coatings processed by different thermal spray processes. Hybrid Advances. 2024; 5: 100125. doi: 10.1016/j.hybadv.2023.100125
[24]Wei Z, Wu Y, Hong S, et al. Effect of WC-10Co on cavitation erosion behaviors of AlCoCrFeNi coatings prepared by HVOF spraying. Ceramics International. 2021; 47(11): 15121-15128. doi: 10.1016/j.ceramint.2021.02.070
[25]Xiao M, Nai S, Nan S, et al. Preparation, mechanical properties and wear resistance of dual-sized TiC particles reinforced high-entropy alloy cermet coating. Journal of Materials Research and Technology. 2024; 28: 97–109. doi: 10.1016 /j.jmrt.2023.11.264
Copyright (c) 2024 Androw D. H., Ratchagaraja Dhairiyasamy
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors contributing to this journal agree to publish their articles under the Creative Commons Attribution 4.0 International License, allowing third parties to share their work (copy, distribute, transmit) and to adapt it for any purpose, even commercially, under the condition that the authors are given credit. With this license, authors hold the copyright.